Abstract

Gas–solid interactions and surface intermediates evolution after NO adsorption onto calcined Ce 0.62Zr 0.38O 2 were investigated. The results of adsorption and temperature-programmed desorption of NO were explained using diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS) coupled with temperature-programmed experiments in environmental cell. Surface NO-containing species such as nitrites and nitrates were identified during evolution of NO on the surface of Ce 0.62Zr 0.38O 2 solid solution at low and high temperature. The ceria–zirconia solid solution was found to be active in deNO x reaction in the presence of a “toluene, propene and propane” mixture.

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