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Abstract
The title compound, (C11H14N4O4)[SbCl4]·H2O, comprises a protonated doxofyllinium cation [7-(1,3-dioxolan-2-ylmethyl)-1,3-dimethyl-2,6-dioxo-3,7-dihydro-1H-purin-9-ium], an [SbCl4]− anion and a water molecule linked by N—H⋯O and O—H⋯Cl hydrogen bonds: the [SbCl4]− anions form centrosymmetric dimers via weak Sb⋯Cl interactions [Sb⋯Cl = 3.1159 (9) Å]. The geometrical arrangement in the crystal structure is characterized by slipped π–π stacking of the parallel purine ring systems, with an interplanar separation of 3.32 Å.
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