Abstract
The structure of dihydronium [catena-bis(μ-pyrazine-2,3-dicarboxylato-N,O,O′)zinc(II)], (H3O)2[Zn(2,3PZDC)2], is composed of polyanionic ribbons of zinc(II) ions linked by double bridging 2,3-PZDC ligand molecules. Each ligand uses an N,O bonding moiety formed by one carboxylic group [Zn–O 2.071(2) Å; Zn–N 2.184(2) Å] and a monodentate oxygen atom of the other carboxylate group [Zn–O 2.092(2) Å]. Coordination around the zinc(II) ion is strongly distorted octahedral. Hydronium cations (H3O)1+ link the ribbons by hydrogen bonds.
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