Abstract
A series of new double orthophosphates of cerium and mono- and divalent elements ACe2(PO4)3, B0.5Ce2(PO4)3, and B1.5Ce1.5(PO4)3 (A = Li, Na, K, Rb, and Cs; B = Mg, Ca, Sr, Ba, and Cd) were synthesized and characterized by X-ray diffraction and IR spectroscopy. The thermal behavior of the phosphates was studied. General crystallochemical features of phase formation in the series of stoichiometric ortho-phosphates of 4f and 5f elements are discussed.
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