Abstract
Abstract In the presence of AlCl3, a mixture of hydrogen azide and tetramethallyltin underwent 1,4- and subsequently 1,2-addition, respectively, with α,β-unsaturated aldimines to give 1,3-amino azides in good yields. The 1,3-amino azides thus obtained were readily converted into 1,3-diamines by reduction with LiAlH4.
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