Abstract
AbstractA double azido‐bridged CuII dinuclear complex with the chelating chiral ligand, [Cu2(L)2(N3)4] (1) [L = (+)‐2, 2′‐isopropylidene‐bis((4R)‐4‐benzyl‐2‐oxazoline)] was synthesized and characterized by single‐crystal X‐ray diffraction, IR spectroscopy, magnetic measurements, and theoretical studies. The asymmetric double end‐on azido bridges in complex 1 lead to a weak antiferromagnetic behavior with J = –7.4 cm–1. The exchange interactions in complex 1 were investigated by DFT calculations, and the calculated exchange interaction (J = –8.0 cm–1) is in good agreement with the experimental value.
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