Abstract

In this work, the cold crystallization peak in DSC analysis is used as a probe to study the structure in amorphous regions of poly(ethylene terephthalate) (PET). The appearance of double cold crystallization peaks for PET samples properly treated at low temperature reveals the co-existence of two kinds of amorphous regions: interlamellar amorphous regions with some order and complete amorphous regions between spherulites.

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