Dosimetric sensing and optical properties of ZnO–SnO2 nanocomposites synthesized by co-precipitation method

Abstract

In this study an effort has been made to investigate the dosimetric sensing and optical properties of ZnO–SnO2 nanocomposites at different pH values. The nanocomposites samples are irradiated by X-ray and then thermoluminescence (TL) analysis is carried out to investigate the response. The structural details of nanocomposites are characterized by Scanning Electron microscope, X-Ray Powder Diffraction and Fourier Transform Infrared Spectroscopy. Similarly, optical properties were characterized by UV–vis spectroscopy and Photoluminescence spectroscopy. The XRD studies revealed good crystallnity of samples with presence of both phases, ZnO as well as SnO2 simultaneously. The SEM image revealed nanoflakes and nanoflower shape of ZnO–SnO2 nanocomposite for sample synthesized at pH 7. Also, nanocube and nanosphere can be seen at higher pH value of 9. The room temperature photoluminescence spectra of ZnO–SnO2 nanocomposite contain multi peaks at 398nm, 410nm, 451nm, 469nm, 484nm, 493nm and 545nm at an excitation wavelength of 225nm, which arises mainly due to oxygen and zinc related defects. The TL glow curve shows intense glow peaks at 346°, 261°, 209° and 153° for the samples synthesized at pH 3, pH 5, pH 7 and pH 9 respectively. The peaks are found to be increased with higher pH values. The peaks are found to be shifted towards lower temperature with higher pH values. The study shows that the ZnO–SnO2 nano-composite is more developed material than singly ZnO compound or SnO2 with enhanced opto-electronic and thermal properties and great applications in thermal dosimetry.