Doppler-limited dye laser excitation spectroscopy of the DSO radical

Abstract

The A ̃ 2A′(003) ← X ̃ 2A″(000) vibronic transition (16 370 to 16 425 cm −1) of the DSO radical in studied by Doppler-limited dye laser excitation spectroscopy. DSO is produced in a flow system by reacting the products of a microwave discharge in O 2 with D 2S. About 637 observed lines are assigned to 987 transitions of the 19 subbands: K′ a ← K″ a = 6 ← 5, 5 ← 4, 4 ← 3, 3 ← 2, 2 ← 1, 1 ← 0, 0 ← 1, 1 ← 2, 2 ← 3, 3 ← 4, 0 ← 0, 1 ← 1, 2 ← 2, 3 ← 3, 4 ← 4, 3 ← 1, 2 ← 0, 0 ← 2, and 1 ← 3. They are analyzed to determine rotational constants, centrifugal distortion constants, and spin-rotation constants for both the ground and the excited electronic states. The band origin obtained is 16 413.874 (2.5σ = 0.002) cm −1. The rotational constants determined are combined with the previous result on HSO (M. Kakimoto et al., J. Mol. Spectrosc. 80, 334–350 (1980)) to calculate the structural parameters for this radical in both the states: r( SO) = 1.494(5) A ̊ , r( SH) = 1.389(5) A ̊ , and ∠HSO = 106.6(5)° for the X ̃ 2A″ state, and r( SO) = 1.661(10) A ̊ , r( SH) = 1.342(8) A ̊ , and ∠HSO = 95.7(21)° for the A ̃ 2A′(003) state, where values in parentheses denote 2.5σ.