Doping effects of alkaline earth element on oxygen reduction property of high-entropy perovskite cathode for solid oxide fuel cells

Abstract

The nearly infinite arrangement and combination of multiple components in high entropy materials provide a huge platform for the modification and performance regulation of new materials. It is an attractive idea to introduce the concept of high entropy into material design and improve its electrochemical performance through component regulation. In this paper, cobalt-based high-entropy perovskite oxides with different alkaline earth metal contents were successfully synthesized. The phase structure, direct current conductivity, oxygen mobility characters and electrochemical properties of these materials are studied. It is found that with the continuous substitution of rare earth elements by alkaline earth elements in high-entropy materials, the content of oxygen vacancies increases and the electrochemical performance is enhanced. The chemical oxygen diffusion coefficient (Dchem) and surface exchange coefficient (Kchem) of the high-entropy oxide La0.2Pr0.2Ba0.2Sr0.2Ca0.2CoO3 are 2.8 × 10−6 cm2 s−1 and 9.1 × 10−3 cm s−1 at 700 °C, respectively. The electrochemical impedance spectroscopy measurement results show that La0.2Pr0.2Ba0.2Sr0.2Ca0.2CoO3 has the minimum polarization resistance, which is 0.03 Ω cm2 at 700 °C in air. The anode-supported fuel cell with the high entropy oxide reaches a peak power density of 792 mW cm−2 at 700 °C and exhibits attractive long-term stability and excellent CO2 resistant properties.