Doped ceria anode interlayer for low-temperature solid oxide fuel cells with nanothin electrolyte

Abstract

Gadolinium-doped ceria (GDC) deposited by radio frequency magnetron sputtering is utilized as the anode interlayer for low-temperature solid oxide fuel cells (LT-SOFCs) with a nanothin yttria-stabilized zirconia (YSZ) electrolyte and Ni/Pt electrodes. When the thickness ratio of YSZ electrolyte versus 100nm GDC anode interlayer is at or below 1.5, the electrochemical performance of the LT-SOFC is severely poor due to the microstructural instability of the GDC anode interlayer under high-temperature reducing atmospheric conditions. At 500°C, the peak power density of the LT-SOFC with a Ni anode and a 20nm GDC anode interlayer is ~30% higher than that without the GDC anode interlayer due to faster reaction kinetics on the anode side.