Abstract

A domino Michael/Michael reaction of 2‐(2‐formylethyl)naphthalene‐1,4‐dione and nitroalkene was catalyzed by diphenylprolinol silyl ether to afford functionalized spiro[cyclopentane‐1,2′(1′H)‐naphthalene] derivatives with four continuous stereocenters in good yields with excellent diastereo‐ and enantioselectivities.

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