Dolomites as SO2 Sorbents in Fluid Combustion Technology

Elżbieta Hycnar,Tadeusz Ratajczak,Magdalena Sęk

doi:10.3390/resources9100121

Abstract

Dolomites are not used as SO2 sorbents in fluid combustion technology. The literature data show fundamental discrepancies in the possibility of such use. They mainly concern the role of magnesium in the sorption process of SO2 and the durability of desulfurization products under high-temperature conditions. The article demonstrates that MgO is actively involved in the SO2 binding under fluidized furnace conditions. The resulting products of sulfation contain magnesium in their compositions, and their thermal transformations begin only after the temperature exceeds 1100 °C. It has been shown that dolomites are a potential raw material for the production of SO2 sorbents for fluid combustion technology, and their use is justified due to the higher desulfurization efficiency. Parameters of dolomite descriptions were given, by which it will be possible to predict the effects of flue gas desulfurization before the dolomites’ use in industrial conditions. It has been shown that there are opportunities to expand the domestic raw-material base for the production of SO2 sorbents, based on both dolomite resources present in deposits and dolomite waste accumulated in dumps, as well as generated during the current exploitation and processing of dolomites.

Highlights

Poland is a country rich in dolomites
31 December 2019 amounted to 498.9 million tonnes, of which 204.8 million tonnes are the resources of exploited deposits
The material used in the studies represents high-quality dolomites with a CaCO3 and MgCO3 at the level of 48–57% wt. and 40–49% wt. respectively (Table 3)

Summary

Introduction

Poland is a country rich in dolomites. The national geological balance resources of dolomites as at31 December 2019 amounted to 498.9 million tonnes, of which 204.8 million tonnes are the resources of exploited deposits (which constitutes 41.0% of the balance resources). Poland is a country rich in dolomites. The national geological balance resources of dolomites as at. 31 December 2019 amounted to 498.9 million tonnes, of which 204.8 million tonnes are the resources of exploited deposits (which constitutes 41.0% of the balance resources). The prospective resources are estimated at 504.2 million tonnes. The forecast resources are estimated at 504.2 million tons. The mentioned occurrences form a rock series extending over large areas and characterized by a variety of mineralogical and chemical characters. This is reflected in the variability of quality parameters within the documented deposits, imposing the need to separate areas suitable for different applications [1,2]

Methods

Results

Conclusion