DME/Air 비예혼합화염의 NOx 생성특성

Abstract

The NOx emission characteristics of DME in laminar coaxial jet and counterflow nonpremixed flames were investigated using experimental and numerical approaches, respectively. The flame structure and NOx emission of DME were compared with those of C₂H? and C₃H?. The DME flame was calculated using the Kaiser’s mechanism, while the C₂H? and C₃H? flames were calculated using the C₃ mechanism. These mechanisms were combined with the modified Miller-Bowman mechanism for the analysis of NOx. Experimental results show in coaxial jet flame that DME flame has the characteristics of partial premixed flame and the flame length decreases up to 1/3 than that of C₃H? in the same condition of fuel mass flowrate. Then, the NOx emission of DME decreases to 40% approximately, comparing with that of C₃H?. In the calculated results of counterflow nonpremixed flame, DME flame shows the EINO decreases up to 50% approximately than those of C₂H? and C₃H? flames when the equivalent fuels are consumed per unit mass and time. Although the overall NOx reaction path of DME is similar with other hydrocarbon fuels, it can be identified that DME flame has a distinct NO reduction mechanism due to the reburning NO chemistry in fuel rich region. From these results, we can conclude that the different NOx emission characteristics of DME flame with other hydrocarbon fuels are attributed to not the temperature increase and the activation of NO reactions due to O atom in DME fuel but the rapid processes of pyrolysis/oxidation.