Diurnal observations of HCl altitude variation in the 70–100 km mesosphere of Venus

Abstract

First submm spectroscopic observations of the 625.9 GHz H35Cl absorption lines of the Venus dayside atmosphere were obtained with the James Clerk Maxwell Telescope (JCMT) on March 2, 2013. These data, which support retrieval of HCl altitude distributions in the Venus mesosphere (70–100 km), are presented here and compared with previously reported JCMT observations of Venus nightside HCl (Sandor et al., 2012). The measured dayside profile agrees with that of the nightside, indicating no diurnal variation is present. More specifically, the nightside spectra revealed a secular decrease of upper mesospheric HCl between observations one month apart, at fixed latitude and local time. The dayside profile reported here presents upper mesospheric abundances that are bracketed by the two previously measured nightside profiles, indicating that if diurnal variation is present, it must be weaker than the secular variations occurring at fixed local time. The previous study, which measured nightside HCl abundances above 85 km to be much smaller than predicted from photochemical modeling, suggested a dynamical explanation for the disagreement wherein nightside downwelling associated with the SubSolar to AntiSolar (SSAS) atmospheric circulation might suppress upper mesospheric abundances predicted purely from photochemistry. However a straightforward prediction from the proposed mechanism is that HCl abundance on the dayside, where the SSAS drives upward rather than downward transport should at least agree with, and perhaps exceed that of the photochemical model. The finding that dayside HCl abundance agrees with that of the nightside, hence also is much smaller than that of the model shows the SSAS hypothesis to be incorrect.