Abstract
The nonuniformity of active sites of a titanium-containing catalytic system in terms of their stereoregulating ability and kinetic activity during butadiene polymerization was studied. It was shown that active sites of three types differing in stereoregulating power and kinetic activity can be formed under polymerization conditions corresponding to the maximum catalyst activity. By solving inverse kinetic problems, the rate parameters for active sites of different types were obtained.
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