Distribution profile of heavy metals and associated contamination trend with the sedimentary environment of Pakistan coast bordering the Northern Arabian Sea.

Abstract

Spatiotemporal distributions of heavy metals (HMs) and their contamination status linked with the sedimentary environment were investigated in 2 monitoring years (MY-I and MY-II) along the Pakistan coast. The concentrations of HMs in sediments were analyzed through an atomic absorption spectrometer and presented the following order: Fe > Zn > Cu > Pb ≈ Cr > Ni > Co > Cd in MY-I and Fe > Cr > Zn > Ni > Cu > Pb > Co > Cd in MY-II. In the coastal sediments, all HMs surpassed the edges of shale values and sediment quality guidelines, excluding Fe. The burial flux (FB), mass inventory (MI), and deposition flux (FD) of HMs were evaluated and compared to explore the potential of sediments to adsorb and desorb the metals into the marine environment during the last decade. Metal-specific pollution indices (Igeo, EF, Cf, and Er) presented moderate contamination of Cu, Zn, Cr, Ni, and Co but considerable contamination of Pb and Cd in sediments. However, site-specific geoindicators (CD, RI, and PLI) signified the Sandspit as the highest polluted site along the coastal vicinity. Multivariate analyses via principal component analysis (PCA) and cluster analysis (CA) also highlighted the significant interactions between geochemical properties. The current study concluded the high pollution state toward the HMs and rendered the knowledge for policymaking and conserving the coastal and estuarine environment of Pakistan bordering the Northern Arabian Sea.