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Abstract
The distribution of phenoxyacetic acid in two-phase organic solvent-water systems and its dimerization in the organic phase were studied. Organic solvents were normal aliphatic alcohols (C5–C10), benzene, and its derivatives. The distribution (K dis) and dimerization (K dim) constants of this acid were determined. The correlations of these quantities with physicochemical parameters of the organic solvents were revealed. The influence of the organic solvent polarity, pH of the aqueous phase, and acid concentration on the physicochemical behavior of the acid in the two-phase systems was analyzed.
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