Distribution behavior and carcinogenic level of some polycyclic aromatic hydrocarbons in roadside soil at major traffic intercepts within a developing city of India

Abstract

A study of polycyclic aromatic hydrocarbons (PAHs) pollution in roadside soil was conducted at a developing city locations of Jalandhar (Punjab), India in winter season to ascertain the contamination levels and their distribution behavior in roadside soil. PAHs concentration level of ten locations was measured at 1, 2, and 3 m distances from roadside soil covering all the major traffic intercepts within a city. Samples were extracted in acetone and dichloromethane (1:1) using soxhlet extraction. The extracts were filtered on a silica gel micro column to remove impurities and eluate was subjected to GC-FID. The total average PAHs concentration (city average) was found to be 4.04 μg g(-1), whereas the concentration of 16 individual PAHs was found to vary between 0.008 and 28.4 μg g(-1). The average concentration of noncarcinogenic and carcinogenic PAHs in all the samples was 2.17 and 6.41 μg g(-1) (ratio 1:2.95). The concentration of five ringed PAHs was found to be 45% to 60%, whereas two ringed PAHs were found to be in the range from 0.28% to 0.56% in all most all locations. The average highest PAHs concentration for any individual location was found as 12.23 μg g(-1) at DAV Chowk at 1 m distance and minimum concentration was 0.98 μg g(-1) at Maqsuda Chowk at 1 m distance from roadside. DiB (ah) A was the individual PAHs found in highest concentration in all the intercepts ranging between 1.26 and 28 μg g(-1). At most of the city intercepts, total carcinogenic PAHs concentration was found to range from 60% to 80% in comparison to noncarcinogenic PAHs (20%-40%) at most of the intercepts. The pollution level our study was compared with other cities of India/worldwide.