Distribution and source analysis of soil toxic organic compounds of coal-electricity production base in arid and semi-arid region of China

Abstract

The presence and distribution of toxic organic compounds in soil pose significant challenges. Whether their distributional characteristics are more complex, especially in arid and semi-arid regions with harsh climatic conditions? This study analyzed the composition, classification, spatial distribution, and sources of 123 toxic organic compounds in 56 soil samples of coal-electricity production base. Those compounds were classified into 11 categories, mainly pesticides (41 compounds), organic synthesis intermediates (31 compounds), and drugs (23 compounds). Seventeen of those compounds were detected over the rate of 30 %, with 13 of them being under the Toxic Substances Control Act (TSCA) inventory. The primary sources of toxic organic compounds were determined using Principal Component Analysis (PCA) and Positive Matrix Factorization (PMF), including the degradation of pesticide residues (22.03 %), emissions of plastic pellets (16.64 %), industrial waste emissions (12.80 %), emissions from livestock (12.74 %), plastic films (11.22 %) and coal-to-liquid projects (10.78 %). This research underscores the widespread presence of toxic organic compounds in soil, highlighting their origins and distribution patterns, which are essential for developing targeted environmental management strategies in arid and semi-arid regions.