Year-end Sale % OFF 
Abstract
The crystal and molecular structures of a “guest–host” complex of cucurbituril with 4‐methylpyridinium, {(4‐MePyH) ⊂ (C36H36N24O12)}(NO3) · 4H2O, were determined by X‐ray structural analysis. The crystals are monoclinic with a = 26.276(3) A, b = 25.861(2) A, c = 17.375(2) A, β = 124.17(1)°, Vcell =9768.6(18) A3, space group Cc, and Z = 8. The structure contains two crystallographically independent supramolecular complexes. They are arranged in pillars oriented along the a axis. In each pillar, the complexes are parallel to each other. The pillars are shifted with respect to each other by one‐half of the crystallographic translation. The centers of the supermolecules are arranged according to a pseudo‐body‐centered motif. Distortions of the cucurbituril molecule depending on the guest type have been analyzed with the use of results obtained in the present and previous studies.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
