Abstract

AbstractAn approach for the distal construction of a C(sp3)−SCF2R bond on aliphatic alcohols enabled by 1,5‐hydrogen‐atom transfer (HAT) was developed. In the presence of a hypervalent iodine (PIDA) and readily available ArSO2SCF2R reagents, this transition metal‐free approach allowed the remote functionalization of a broad variety of alcohols with emergent and high added‐value SCF2R moieties (R=H, F, CO2Et and PO(OEt)2) under blue light irradiation.magnified image

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