Abstract

This study reports on a single-track laser surface alloying process that utilizes SiO2 powder to disperse both SiO2 particles and oxide inclusions in 316L stainless steel for oxide dispersion strengthening (ODS) purposes. In this process, the SiO2 powders partially dissolve in the melt pool, and the released silicon and oxygen atoms nucleate to form oxide inclusions in-situ within the metal matrix. This dissolution-induced oxide synthesis route demonstrated a high potential for ODS, achieving a high particle number density (6.6 × 104 mm−2) and area fraction (3.3%) comparable to that of bulk 316L samples produced via directed energy deposition. The hardness of the SiO2/316L composites reached a maximum of 232.4 HV compared to that of the 316L substrate (average 170.8 HV). The improvement in hardness was theoretically explained and quantified, significantly originating from the enhanced dislocation density strengthening mechanism resulting from the large difference in the coefficient of thermal expansion between SiO2 and 316L.

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