Dissolution and Deagglomeration of Silicon Nitride in Aqueous Medium

Abstract

Silicon nitride undergoes hydrolysis and dissolution when subjected to an aqueous environment. Molecular dynamics simulations suggest that hydrolysis proceeds through nucleophilic attack of water with the formation of an intermediate molecular complex involving a pentacoordinated silicon. We found that the dissolution of an oxidized silicon nitride powder resembles that of silica; the dissolution rate could be described using a simple kinetic equation with a dissolution activation energy of 52 kJ·mol−1. The deagglomeration of a fine silicon nitride powder under mild agitation was evaluated; we show that the peptization kinetics at room temperature is dominated by the breakup of particle–particle bonds due to hydrodynamic friction and cluster attrition. For breakup of hard agglomerates of small particles the dissolution of interparticle necks will play an important role.