Dissociative Photodetachment Studies of I2-·Ar: Coincident Imaging of Two- and Three-Body Product Channels

Abstract

Van der Waals clusters serve as prototypical systems for studying processes of energy transfer. The I2.Ar system has attracted particular interest due to the wide array of decay processes occurring in competition with one another. Here, we present systematic dissociative photodetachment (DPD) studies of the I2- and I2-.Ar anions in the region 4.24-4.78 eV. The resulting neutral fragments are detected by time- and position-sensitive (TPS) coincident imaging. Photofragment mass distributions and translational energy distributions from the DPD of I2- are presented and facilitate understanding of the I2.Ar system. For the I2.Ar complex, channels resulting from two-body dissociation leading to I2+Ar photoproducts are observed at all photon energies employed. We also report the first direct observation of the previously inferred three-body dissociation channel leading to I+I+Ar photoproducts. The relative intensities of each decay channel are investigated in relation to the electronic state being accessed. Translational energy distributions of the I2.Ar complex lend further insight into the decay mechanism for each channel.