Abstract

The excitation transfer from Ar* to SiH 4 has been studied by observing UV and visible emission in a flowing afterglow and beam apparatus. The emission rates of Sill (A 2Δ) and Si* atoms have been determined. From the nascent rovibrational distribution of SiH(A), the fractions of the available energy deposited into vibration and rotation of SiH(A) were estimated to be 2.9% and 4.4%, respectively.

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