Abstract
Electron impact ionization of dinitrogen pentoxide for incident electron energies up to about 25 eV has been investigated by use of a crossed beams quadrupole mass spectrometer system. The experiments reported in this paper detected the fragmentation products NO 2 +, NO +, O +, N +, and NO 3 +. No stable N 2O 5 + ion was observed. The NO 3 + fragment, for which we determine an appearance energy 13.25±0.30 eV, has not been observed previously. This appearance energy is close to the calculated threshold.
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