Abstract
The formation of S − and C − ions from electron impact on OCS has been investigated by using a crossed electron beam-molecular beam collision geometry. Measured appearance energies and peak energies for the formation of S − and C − ions are reported. These data were then used to identify the various channels of dissociation by employing Hess's law. It is shown that OCS, although isoelectronic in the valence shell, does not conform in its attachment properties to CO 2 and CS 2.
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