Abstract

The thermodynamic calculations of dissociation of LiAlO 2 and LiGaO 2 as function of temperature and oxygen pressure are presented. It has been found that LiGaO 2 evaporates congruently at the melting point under the oxygen pressure equal to 1.10 -5 atm. LiAlO 2 evaporates incongruently, the equilibrium oxygen partial pressure at the melting point is equal to 9.6.10 -5 atm and the partial pressure of Li and Al oxides decrease with increasing of oxygen pressure.

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