Abstract
Experimental potential energy curves for the electronic ground states of SO +, SF and PBr have been constructed by using the methods of Rydberg-Klein-Rees, as modified by Vanderslice et al., as well as the authors' modification of the method of Vaidyan and Santaram. The dissociation energies of the ground states have been obtained by a curve fitting procedure using an empirical potential function with the RKRV potential energy curves. The estimated values of the dissociation energies are 5.43 ± 0.19, 3.30 ± 0.10 and 4.46 ± 0.14 eV for SO +, SF and PBr, respectively.
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