Abstract
The present photoelectron—photoion—photoion coincidence measurement indicates that the dynamics of ion-pair production following the discrete resonance excitation B 1s → 2a″ 2 are completely different from those following the B 1s ionization and the direct double photoionization. The difference is attributed to deformation of the core-excited 2a″ 2 state with the help of ab initio SCF calculation.
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