Abstract
A coincidence study between energy-selected electrons and mass- and energy-selected ions shows that dissociation from the spectator-Auger-final states both above and below the double ionization threshold produces energetic B + whereas dissociation following B 1 s ionization produces energetic F +. An angle-resolved photoion study reveals that the B + is ejected from the spectator-Auger-final states of the deformed C 3 v pyramidal molecule, after the neutral F ejection but before the free molecular rotations, whereas the B + ejection following the B 1 s ionization is within the D 3 h plane of the parent molecule.
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