Dissecting the Triplet-State Properties and Intersystem Crossing Mechanism of the Ligand-Protected Au13 Superatom.

Abstract

Icosahedral Au13 nanoclusters are among the most typical superatoms and are of great interest as promising building blocks for nanocluster-assembled materials. Herein, the key parameters involved in the intersystem crossing (ISC) process of [Au13(dppe)5Cl2]3+ (Au13; dppe = 1,2-bis(diphenylphosphino)ethane) were characterized. Quenching experiments using aromatic compounds revealed that the T1 energy of Au13 is 1.63 eV. An integrative interpretation of our experimental results and the relevant literature uncovered important facts concerning the Au13 superatom: the ISC quantum yield is unity due to the ultrafast ISC (∼1012 s-1), the lowest absorption band includes contributions of direct singlet-triplet transitions, and there exists a large S1-T1 gap of 0.73 eV. To explain the efficient ISC, the El-Sayed rule was applied to the superatomic orbitals corresponding to the excited-state hole/electron distributions obtained from theoretical calculations. The strong spin-orbit coupling between the S1 and T2-T4 states offers a reasonable explanation for the ultrafast ISC.