Abstract
Major waste products from fertilizer manufacture are calcine and so-called phosphogypsum, calcium sulphate. The oxidation and leaching of calcine produces a liquid with a high acidity and hence is acid generating. Disposal of phosphogypsum, an acid-bearing waste, is normally effected by construction of a tailings impoundment, similar in nature to those utilized for tailings disposal in the mining industry.This paper addresses the general chemistry, pollution potential, and chemical attack potential of both calcine and phosphogypsum and the impact these have on their disposal. The similarities and differences in the design philosophy for acid-bearing and acid-generating waste facilities are then discussed. Key words: phosphogypsum, acid sludge, fertilizer manufacture, water pollution, waste disposal, calcine, sulphuric acid manufacture.
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