Dispersion Phenomena in Thermal Diffusion and Modelling of Thermogravitational Experiments in Porous Media

Abstract

In a TIPM paper published in 1992, the authors presented a simple model of thermogravitational diffusion in packed columns (TPC). Though qualitatively in agreement with the experimental results, this model exhibited a systematic discrepancy with respect to the magnitude of the permeability of maximum separation in the TPC experiments. Here, the results of a re-examination of the classical phenomenology of irreversible thermodynamics in porous media, applied to TPC, are described. Through the interpretation of additional TPC experiments, we show that the effective thermal diffusion coefficient in TPC includes a dependency upon the fluid velocity. This dependency is consistent with a nonlinear extension of irreversible thermodynamics, and the model so amended accounts for a correct re-interpretation of the experiments.