Abstract

1. The dispersion of the optical rotation and UV absorption spectra of derivatives of gramicidin S with heavy atoms in solutions of ethanol was studied. 2. All the derivatives studied have a similar and rather rigid conformation. 3. A lack of correspondence between the data on the dispersion of the optical rotation and the structure of gramicidin S in the form of fragments of anα-helical conformation, proposed by certain authors, was established.

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