Dispersion Dynamics of Clustered Particles by Centrifugal Force

Abstract

In this paper an approach is proposed to solve the problem of aggregation in nanomaterials through the mean of rotational separation aiming to quickly disperse clustered nanoparticles while not affecting their purity. If it is possible, this approach may replace the current mean of mechanical mixing, which may cause impurities issues. The hypothesis is that the centrifugal force due to rotational velocity acting on the nanoparticles can overcome the cohesive force between the nanoparticles, therefore dispersing the clustered nanoparticles. The experimental mean is to put different spheres connected by different types of glues imitating different nanoparticle clusters into centrifuges imitating the swivel plate. The results from both the theoretical model and the experiment show that for a cluster with a cohesive force of 1.75N, a rotational velocity of about 800rad./s is required to disperse the cluster. While for a cluster with a cohesive force of 0.25N and the same mass and position, a rotational velocity of about 150 rad./s is required to disperse the cluster. Except for the cohesive force, the mass and position of the nanoparticle on the swivel plate also have a large effect on the required rotational velocity. The observation of the physical mechanism of the dispersion has also shown that while using this way, the cluster is dispersed slowly with small parts separated from it. Therefore, this way can also eliminate re-clustering problems of nanoparticles.