Abstract

The dispersion ( I M) and selectivity ( I) indices of homologous alkyl, (ω-chloroethyl and alkenyl benzoate and monochlorobenzoate esters are presented as obtained on low polarity (SE-30) and polar (OV-351) capillary columns. The effects of alkyl chain length, unsaturation and the position of chlorination are discussed and the results compared with studies of aliphatic esters. The compounds considered allow a study of the effect upon retention of chlorination in both the aromatic ring and the alkyl group.

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