Dispersibility of γ-MPS-modified silica sol particles in an ethanol–water mixed solvent

Abstract

The dispersibility of silica sol particles modified by γ-methacryloxy propyl trimethoxyl silane (γ-MPS) in an ethanol–water mixed solvent was investigated. In the modification process, the hydrolysate of γ-MPS condensed to form oligomers, which further formed hydrogen bonds with the hydroxyl groups on the surface of the silica sol particles to cause agglomeration. Increasing the ethanol concentration inhibited the hydrolysis of γ-MPS and the formation of oligomers, thus inhibiting the agglomeration of silica sol particles. When the ethanol concentration was above 74 wt%, the γ-MPS-modified silica sol slurry was transparent and with a TEM image in a single-particle dispersed state. The dispersibility of the silica sol particles was determined by a double electric layer repulsion mechanism before modification and a steric hindrance mechanism by organic molecules grafted on the surface of the particles after modification. The grafting density of γ-MPS on the surface of silica sol particles affected the hydrophobicity of the modified particles, which can be effectively controlled.