Abstract
AbstractCrystallite orientation in polyethylene has been investigated in the high range of stretching. Crystallite disorientation can be observed in samples subjected to various stretching procedures: hot drawing and elongation of oriented fibers at room temperature at constant rate and at constant load. Crystallite disorientation does not take place during elongation but is induced upon removal of the applied stress. The higher the rate of removal of stress the greater is the disorientation. Two mechanisms are postulated for the disorientation: one relating to the irregular residual strain developed in fibrils by high stretching, and the other concerning rotational movement of crystallites caused by amorphous chains terminated on the interfaces. The fibrillation brought about by high stretching is thought to play an important role in the crystallite disorientation.
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Schedule a callMore From: Journal of Polymer Science Part A-2: Polymer Physics
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