Abstract

Fluorine mobility in monocrystalline LaF 3 is analyzed using 19F NMR spectroscopy. At lower temperatures the motion is restricted to F − ions in the F 1 sublattice and characterized by a strongly heterogeneous behavior. Our approach which is based on line shape analysis shows that the mobility can be well described by a broad distribution of correlation times. The distribution of the correlation times and its variation with the temperature reflects the potential energy landscape in the superionic state.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call