Disjoining Pressure Measurements for Foam Films Stabilized by a Nonionic Sugar-Based Surfactant

Abstract

Disjoining pressure isotherms for foam films made from a nonionic surfactant, octyl β-glucoside, are measured at different surfactant concentrations, ionic strengths, and solution pH values. Below the cmc an electrostatic double-layer repulsion is present and dominates the long-range interaction. The decay length of the forces agrees with the expected Debye length and the measured long-range interactions are consistent with solutions to the nonlinear Poisson−Boltzmann equation using constant charge conditions. The deduced surface charge densities increase with pH and ionic strength but decrease with increasing surfactant concentration. At, or just above, the cmc, surfactant covers the interface and suppresses the charge sufficiently to induce a transition from a common black film to a Newton black film. Ultimately, the film stability is determined by both surface forces and elasticity. Combining both, via an overall film tension, leads to a general expression for the film elasticity.