Abstract
On the basis of the atomic-coordination−atomic-radius correlation (Feibelman, P. J. Phys. Rev. B 1996, 53, 13740. Goldschmidt, V. M. Ber. Dtsch. Chem. Ges. 1927, 60, 1270.) and its perturbation of the Hamiltonian of an extended solid, we have developed an effective yet straightforward method to determine the core-level energies of an isolated atom and the crystal-binding intensities of the core electrons at energy levels shifted by bulk formation, surface relaxation, or nanosolid formation. The developed method not only allows the predicted size dependence of core-level shift to match observations but also enables conventional X-ray photoelectron spectroscopy (XPS) to provide comprehensive information about the behavior of electrons in the deeper shells of an isolated atom and the influence of crystal formation.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.