Discrete and polymeric organometallic-organic assemblies based on the diarsene complex [(Cp)2Mo2(CO)4(μ,η2-As2)], AgPF6and N-donor organic molecules

Abstract

The first mixed-ligand self-assembly reactions of the diarsene complex [Cp2Mo2(CO)4(μ,η2-As2)] and N-donor organic molecules in the presence of AgPF6 allow for the synthesis of two discrete and four polymeric supramolecular aggregates.