Abstract

A recently improved three-laser heterodyne system was used to frequency measure ten previously observed optically pumped far-infrared (FIR) laser emissions from the partially deuterated methanol isotopologue CH2DOH. Also, a 64.0 μm FIR emission generated by the 9P32 line of the carbon dioxide (CO2) laser was discovered and frequency measured. These newly measured frequencies have fractional uncertainties on the order of ± 2 × 10 -7 and correspond to laser wavelengths ranging from 42.6 to 152.7 μm. The offset frequency for the CO2 pump laser was measured for twenty-two CH2DOH FIR laser emissions.

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