Discoloration performance and mechanism research of a novel thermochromic energy storage material

Abstract

The combination of phase change materials and thermochromic materials can realize the purpose of changing color while storing energy, so as to play the role of temperature regulation and color warning. In this paper, a thermochromic energy storage material (TESM) was prepared by using crystal violet lactone (CVL) and cresol red (CSR) as color former and color developer each other, taking octadecanol (OD) as the solvent and the energy storage material. The phase transition of OD induces ring-opened and ring-closed of lactone in both CVL and CSR, further leading to better discoloration. The influence of different proportions on the discoloration effect was studied. The thermal properties and functional groups of the samples were characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TG) and Fourier transform infrared spectrometer (FT-IR). The discoloration and re-coloration mechanism were explored. The results showed that the color of the prepared TESM can reversibly change between yellow-green (at room temperature) and red (at high temperature). The discoloration is attributed to the change of the intermolecular force between OD and CSR caused by the solid-liquid phase transformation of OD. When m(CVL): m(CSR): m(OD) = 3:1:500 (B3), the color difference of the prepared TESM is 38.81 NBS and the melting enthalpy is 219.8 J/g. Moreover, the prepared TESM shows good thermal stability and thermal cycling performance, and it has broad application prospects in the field of temperature alert and control.