Disalignment rate coefficient of argon 2p8 due to nitrogen collision

Abstract

Tunable diode laser induced fluorescence (TDLIF) measurements are discussed and quantitatively evaluated for nitrogen admixtures in argon plasma under the influence of a strong magnetic field. TDLIF measurements were used to evaluate light-transport properties in a strongly magnetized optically thick argon/nitrogen plasma under different pressure conditions. Therefore, a coupled system of rate balance equations was constructed to describe laser pumping of individual magnetic sub-levels of 2p8 state through frequency-separated sub-transitions originating from 1s4 magnetic sub-levels. The density distribution (alignment) of 2p8 multiplet was described by balancing laser pumping with losses including radiative decay, transfer of excitation between the neighboring sub-levels in the 2p8 multiplet driven by neutral collisions (argon and nitrogen) and quenching due to electron and neutral collisions. Resulting 2p8 magnetic sub-level densities were then used to model polarization dependent fluorescence, considering self-absorption, which could be directly compared with polarization-resolved TDLIF measurements. This enables to estimate the disalignment rate constant for the 2p8 state due to collisions by molecular nitrogen. A comparison to molecular theory description is given providing satisfactory agreement. The presented measurement method and model can help to describe optical emission of argon and argon–nitrogen admixtures in magnetized conditions and provides a basis for further description of optical emission spectra in magnetized plasmas.