Abstract
a) Absorption transition moment directions of the diphenylphosphinyl (2 a) and methylsulphonyl (3 a) Absorption transition moment directions of the diphenylphosphinyl (2 and methylsulphonyl (3 a) co-substtuted in 4-dimethylamino-trans-styrenes were determined in stretched poylvinyl alcohol (PVA) films based on measurements of the absorption anisotropics. It has been found that the long-wave absorption spectrum consists of two bands corresponding to differently directed transition moments. The transition moment of the intensive long-wave *La band is lies along the long axis of these molecules whereas that of the short-wave band is oriented at (p = 38° for 2 a and q> = 35° for 3 a relative to the transition moment direction of the 1La band-substtuted in 4-dimethylamino-trans-styrenes were determined in stretched poylvinyl alcohol (PVA) films based on measurements of the absorption anisotropics. It has been found that the long-wave absorption spectrum consists of two bands corresponding to differently directed transition moments. The transition moment of the intensive long-wave *La band is lies along the long axis of these molecules whereas that of the short-wave band is oriented at (p = 38° for 2 a and q> = 35° for 3 a relative to the transition moment direction of the 1La band
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
