Direct synthesis of thiol-ligands-functionalized SBA-15: Effect of 3-mercaptopropyltrimethoxysilane concentration on pore structure

Abstract

Mesoporous thiol-functionalized SBA-15 silicas have been directly synthesized by co-condensation of tetraethyl orthosilicate and 3-mercaptopropyltrimethoxysilane with triblock copolymer poly(ethylene glycol)-B-poly(propylene glycol)-B-Poly(ethylene glycol) as structure-directing agent under hydrothermal condition. Mesoporous structure was obtained after the surfactant removal by Soxhlet ethanol extraction. These materials have been characterized by means of powder X-ray diffraction, nitrogen sorption, transmission electron microscopy, thermogravimetry analysis, elemental analysis and solid state 29Si nuclear magnetic resonance. The effect of 3-mercaptopropyltrimethoxysilane concentration in the initial mixture on the pore structure of functionalized SBA-15, including pore ordering, surface area, pore size and pore volume, is investigated in detail. In order to functionalize the SBA-15 silicas without a significant change of pore structure, the molar concentration of 3-mercaptopropyltrimethoxysilane should be limited to less than 20%.