Abstract
AbstractHerein, we report copolymerizations of ethylene (E) and ortho‐/meta‐/para‐fluorostyrenes (SF=oFS/mFS/pFS) by using quinolyl methylene fluorenyl scandium complex (Flu‐CH2‐Qu)Sc(CH2SiMe3)2. The copolymerizations proceed in a controlled fashion to afford copolymers composed of “soft” ethylene‐fluorostyurene (E–SF) random segments (Tg=−22.2–5.1 °C) and “hard” crystalline ethylene–ethylene (E–E) segments (Tm=42.3–130.2 °C). The copolymers behave like thermoplastic elastomers at room temperature by showing high stress values up to 39.5 MPa under elongation‐at‐break above 774 % with elastic recovery over 75 %. The excellent mechanical properties are mainly attributed to the microphase separation of the nanoscale crystalline E–E domain from the amorphous E–SF copolymer matrix proved by AFM, WAXD and SAXS. The mechanism investigation by the density functional theory (DFT) simulation reveals that the steric bulky and electron‐withdrawing ligand of the catalytic precursor prefers E propagation to generate long E–E segments, while the incorporation of SF is thermodynamic control.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.